PUBLICATIONS

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Publications

215) Enantioselective allylic alkylation of stereodefined polysubstituted copper enolates as an entry to

acyclic quaternary carbon stereocentres

 

214) Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

 

213) Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed

Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates

Pavel Starkov, Jared T. Moore, Douglas C. Duquette, Brian M. Stoltz, Ilan Marek

 

212) Tandem Hydroalumination/Cu-Catalyzed Asymmetric Vinyl Metalation as a New Access to Enantioenriched

Vinylcyclopropane Derivatives

Daniel S. Müller, Veronika Werner, Sema Akyol, Hans-Günther Schmalz, and Ilan Marek

 

211) Brook Rearrangement as Trigger for Carbene Generation: Synthesis of Stereodefined and Fully Substituted

Cyclobutenes

Fa-Guang Zhang, Ilan Marek
 

210) Asymmetric Copper-Catalyzed Carbomagnesiation of Cyclopropenes

Longyang Dian, Daniel S. Müller, Ilan Marek

Angew. Chem. Int. Ed. 2017, 56, 6783 –6787

 

209) Merging C–H and C–C bond cleavage in organic synthesis

Zackaria Nairoukh, Morgan Cormier, Ilan Marek

Nature Reviews Chemistry 1, Article number: 0035 (2017)

 

208) Classical and Novel TSPO Ligands for the Mitochondrial TSPO Can Modulate Nuclear Gene Expression:

Implications for Mitochondrial Retrograde Signaling

Nasra Yasin, Leo Veenman, Sukhdev Singh, Maya Azrad, Julia Bode, Alex Vainshtein, Beatriz Caballero, Ilan Marek and Moshe Gavish

Int. J. Mol. Sci. 2017, 18(4), 786

 

207) Merging allylic C-H bond activation and C-C bond cleavage en route to the formation of a

quaternary carbon stereocenter in acyclic systems

Alexandre Vasseur, Ilan Marek

Nature Protocols 12, 74–87 (2017)

 

206) A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening

Sukhdev Singh, Jeffrey Bruffaerts, Alexandre Vasseur, Ilan Marek

Nat. Commun., 2017, 8, 14200

 

205) Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindole

Bo Cao, Marwan Simaan, Ilan Marek, Yin Wei* and Min Shi*

Chem. Commun., 2017,53, 216-219

 

204) Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Sudipta Raha Roy, Hendrik Eijsberg, Jeffrey Bruffaerts and Ilan Marek

Chem. Sci., 2017,8, 334-339

 

203) Oxidation of bis-sulfinyl carbanions as the pivot of ionic/radical tandem reactions

Guillaume Vincent, Saloua Cheli, Rocio Martinez Mallorquin, Adi Abramovitch, Sophie Beauviere, Catherine Gomez,

Franck Brebion, Ilan Marek, Max Malacria, Jean Philippe Goddard, Louis Fensterbank

C. R. Chimie 19 (2016) 403-411

 

202) Zirconocene-assisted remote cleavage of C–C and C–O bonds: application to acyclic stereodefined metalated

hydrocarbons

 

201) Copper mediated carbometalation reactions

D. S. Müller and I. Marek

Chem.Soc. Rev., 2016,45, 4552-4566

 

200) Enantiodivergent Combined Carbometalation − Zinc Homologation – C-C Fragmentation Reaction as an Efficient

Tool to Prepare Acyclic Allylic Quaternary Carbon Stereocenters

Sudipta Raha Roy , Dorian Didier, Amir Kleiner and Ilan Marek

Chem. Sci., 2016, 7, 5989–5994.


199) Formation of Carbon Quaternary Stereogenic Center in Acyclic Systems via a Sequence of Carbometalation −

Intramolecular Cyclization − Silicon Activation

Maya Preshel-Zlatsin, Fa-Guang Zhang, Guillaume Eppe, Ilan Marek

Synthesis 2016, 48, 3279-3286.

 

198) Preparation and Reactivity of Acyclic Chiral Allylzinc Species by a Zinc-Brook Rearrangement

Markus Leibeling, Khriesto A. Shurrush, Veronika Werner, Lionel Perrin, and Ilan Marek

Angew.Chem. Int.Ed. 2016, 55,6057 –6061

 

197) Stereoselective Formation of Fully Substituted Ketone Enolates

Elvira Haimov, Zackaria Nairoukh, Alexander Shterenberg, Tiran Berkovitz, Timothy F. Jamison, and Ilan Marek

Angew. Chem. Int. Ed. 2016, 55, 5517 –5520

 

196) Remote functionalization through alkene isomerization

Alexandre Vasseur, Jeffrey Bruffaerts and Ilan Marek

Nature Chemistry, 2016, 8, 209–219 

 

195) Brook Rearrangement as a Trigger for the Ring Opening of Strained Carbocycles

Fa-Guang Zhang, Guillaume Eppe, and Ilan Marek

Angew. Chem. Int. Ed. 2016, 55, 714–718

 

194) Oxidation of bis-Sulfinyl Carbanion as the Pivot of Ionic/Radical Tandem Reactions

Guillaume Vincent, Saloua Chelli, Rocio Martinez Mallorquin, Adi Abramovitch, Sophie Beauvière, Catherine Gomez, Franck Brebion, Ilan Marek, Max Malacria,Jean Philippe Goddardand Louis Fensterbank

G. Vincent et al. / C. R. Chimie, 2016, 19, 403-411

 

193) Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en Route to the Formation of Diastereo- and

Enantiomerically Enriched Polysubstituted Cyclopropanes

Daniel S. Müller and Ilan Marek

J. Am. Chem. Soc., 2015, 137 (49), 15414–15417

 

192) Carbozincation Reactions of Carbon-Carbon Multiple Bonds

Sklute, G.; Cavender, H.; Marek, I.

Org. React., 2015, 87, 507-763

 

191) Quinazoline-based tricyclic compounds that regulate programmed cell death, induce neuronal differentiation, and

are curative in animal models for excitoxicity and hereditary brain disease

A. Vainshtein, L. Veenman, A. Shterenberg, S. Singh, A. Masarwa, B. Dutta, B. Island, E. Tsoglin, E. Levin, S. Leschiner, I. Maniv, L. Pe’er, I. Otradnov, S. Zubedat, S. Mizrachi, A. Weizman, A. Avital, I. Marek, M. Gavish

Cell Death Discovery, 2015, 1, 15027

 

190) Stereodefined Acyclic Polysubstituted Silyl Ketene Aminals: Asymmetric Formation of Aldol Products with Quaternary Carbon Stereocenters

Zackaria Nairoukh and Ilan Marek

Angew. Chem. Int. Ed., 2015, 54, 14933-14937

 

189) Gold(I)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes

De-Yao Li,a Yin Wei,a Ilan Marek,b Xiang-Ying Tanga and Min Shia  

 

188) Synthesis and Stereochemical Assignment of Crypto-Optically Active 2H6-Neopentane
Dr. Ahmad Masarwa1, Dr. Dennis Gerbig2,Liron Oskar1,Prof. Dr. Aharon Loewenstein1,Dr. Hans Peter Reisenauer2,Prof. Dr. Philippe Lesot3,*,Prof. Dr. Peter R. Schreiner2,* and Prof. Dr. Ilan Marek1,*

Angew. Chem.Int. Ed. 2015, 54,13106 –13109

 

187) The Scientific Bridge: Fifty Years of Germany–Israel Diplomatic Relations

Prof. Dr. Helmut Schwarz1, Prof. Dr. Itamar Willner2,* and Prof. Dr. Ilan Marek3

Angew. Chem. Int. Ed. 2015, 54, 2 4

 

186) Forming Stereogenic Centers in Acyclic Systems from Alkynes
Dr. Roxane Vabre1, Biana Island1,Claudia J. Diehl, Peter R. Schreiner and Ilan Marek
Angew. Chem. Int. Ed. 2015, 54, 9996 – 9999

 

185) Stereocontrolled Formation of Several Carbon–Carbon Bonds in Acyclic Systems
Guillaume Eppe , Dorian Didier , and Ilan Marek
Chem. Rev. 2015, 115, 9175 - 9206

 

184) Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol.

Alexandre Vasseur,a Lionel Perrin,*b Odile Eisensteinc and Ilan Marek*a

Chem. Sci., 2015,6, 2770 - 2776

 

183) Cyclopropene Derivatives as Precursors to Enantioenriched Cyclopropanols and n-Butenals Possessing

Quaternary Carbon Stereocenters.

Marwan Simaan, Dr. Pierre-Olivier Delaye, Prof. Dr. Min Shi and Prof. Dr. Ilan Marek

Angew.Chem. Int.Ed. 2015, 54,12345 –12348

 

182) Gold- and Silver-Catalyzed Intramolecular Cyclizations of Indolylcyclopropenes for the Divergent Synthesis of

Azepinoindoles and Spiroindoline Piperidines.

Peng-Long Zhu, Zhen Zhang, Dr. Xiang-Ying Tang, Prof. Ilan Marek and Prof. Min Shi
ChemCatChem 2015, 7, 595 – 600

 

181) Electrophilic Amination: The Case of Nitrenoids

Dr. Pavel Starkov, Prof. Dr. Timothy F. Jamison and Prof. Dr. Ilan Marek


Chem. Eur.J. 2015, 21, 5278 – 5300

 

180) Selective Carbon–Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems

Prof. Dr. Ilan Marek*, Dr. Ahmad Masarwa, Dr. Pierre-Olivier Delaye and Dr. Markus Leibeling


Angew. Chem. Int. Ed. 2015, 54, 414 429

 

179) Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Enantioselective

Alkynylation of Acylsilanes, Brook Rearrangement, and Ene-Allene Carbocyclization Reactions

Polina Smirnov †, Einat Katan †, Jomon Mathew †, Arseni Kostenko †, Miriam Karni †, Anne Nijs ‡, Carsten Bolm ‡,

Yitzhak Apeloig *†, and Ilan Marek *†


J. Org. Chem., 2014, 79 (24), 12122–12135

 

178) Stereodefined acyclic trisubstituted metal enolates towards the asymmetric formation of quaternary carbon

stereocentres

Yury Minko and Ilan Marek


Chem. Commun., 2014,50, 12597-12611

 

177) Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol

Type Derivatives Bearing a Stereocontrolled Quaternary Center

Lydia Klier, Coura R. Diene, Manuel Schikinger, Albrecht Metzger, Andrea J. Wagner, Konstantin Karaghiosoff, Ilan

Marek and Paul Knochel

Chem. Eur. J. 2014, 20, 14096 – 14101

 

176) Chemistry in Israel−at a Crossroads? (Editorial)

Ilan Marek

Angew. Chem. Int. Ed. 2014, 53, 3754 - 3755

 

175) All-Carbon Quaternary Stereogenic Centers in Acyclic System through the Creation of Several C-C bonds per

Chemical Steps

Ilan Marek, Yury Minko, Morgane Pasco, Tom Mejuch, Noga Gilboa, Helena Chechik, Jaya P. Das

J. Am. Chem. Soc. 2014, 136, 2682 - 2694

 

174) Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents

Zhi-Liang Shen, Zhihua Peng, Chun-Ming Yang, Julian Helberg, Peter Mayer, Ilan Marek and Paul Knochel

Org. Lett.2014, 16, 956−959

 

173) Oxenoids in Organic Synthesis

Yury Minko and Ilan Marek

Organic and Biomolecular Chemistry 2014, 12, 1535-1546.

 

172) Advances in Carbolithiation

Yury Minko and Ilan Marek

In Lithium Compounds in organic Synthesis: From Fundamentals to Applications, First Edition.

Edited by Renzo Luisi and Vito Capriati.

Wiley-VCH (2014), 329-350

 

171) Carbometalation Reactions

Dorian Didier, Ilan Marek

In Copper-catalyzed Asymmetric Synthesis, First Edition.

Edited by Alexandre Alexakis, Norbert Krause and S. Woodward.

Wiley-VCH, (2014), 267-282.

 

170) Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes

Dorian Didier, Pierre-Olivier Delaye, Marwan Simaan, Biana Island, Guillaume Eppe, Hendrik Eijsberg, Amir Kleiner,
Paul Knochel, Ilan Marek*
 
 

169) Merging Allylic C-H Activation and Selective C-C Bond Activation

Ahmad Masarwa, Dorian Didier, Tamar Zabrodsky, Marvin Schinkel, Lutz Ackermann and Ilan Marek*

Nature 2014, 505, 199-203

Highlighted in C&EN, 2013, December 16

Highlighted in Nature Chemistry, 2014, 6, 86

 

 

168) A One-Pot Zinc-promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly

Selective Formation of Three New bonds and two Stereocenters in Acyclic Systems

Polina Smirnov, Jomon Mathew, Anne Nijs, Einat Katan, Miriam Karni, Carsten Bolm, Yitzhak Apeloig, Ilan Marek*

Angew. Chem. Int. Ed. 2013, 52, 13717 - 13721

  

                     

167) Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes

Marvin Schinkel, Jan Wallbaum, Sergei I. Kozhushkov, Ilan Marek, Lutz Ackermann*

Org. Lett. 2013, 15, 4482 - 4484

 

166) Carbometalation Reactions

Yury Minko and Ilan Marek*

in Metal-Catalyzed Cross-Coupling Reactions- Third edition

Eds de Meijere, A., Oestreich, M., Brase, S. Wiley-VCH, (2013)  


 

165) Axial Preferences in Allylation Reactions via the Zimmerman – Traxler Transition State

Tom Mejuch, Noga Gilboa, Eric Gayon, Hao Wang, K. H. Houk, Ilan Marek*

Acc. Chem. Res. 2013, 46, 1659 - 1669.

 

 

164) Diastereodivergent Carbometalation/Oxidation/Selective Ring Opening: Formation of All-Carbon Quaternary

Stereogenic Centers in Acyclic Systems

Pierre-Olivier Delaye, Dorian Didier, Ilan Marek*

Dr. Pierre-Olivier Delaye, Dr. Dorian Didier, Prof. Dr. Ilan Marek*

Angew. Chem. Int. Ed., 2013, 52, 5333 – 5337

 

 

163) Regio- and Stereoselective Carbometallation Reactions of N-Alkynyl-Amides and Sulfonamides

Yury Minko, Morgane Pasco, Helena Chechik and Ilan Marek*

Beilstein J. Org. Chem. 2013, 9, 526 - 532.

162) Stereodefined Trisubstituted Enolates as a Unique Entry to All-Carbon Quaternary Stereogenic Centres in

Acyclic Systems

Yury Minko, Morgane Pasco, Lukas Lecher, Ilan Marek*

Nature Protocols, 2013, 4, 749 - 754.

 

 

161) The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic systems

Morgane Pasco, Noga Gilboa, Tom Mejuch, Ilan Marek*

Organometallics, 2013, 32, 942 - 950

 

 

160) Carboxylate-assisted Ruthenium(II)-Catalyzed C-H Arylation of 5-Aryl Tetrazoles: Step-Economical Access to Valsartan

Emelyne Diers, N. Y. Phani Kumar, Tom Mejuch, Ilan Marek, Lutz Ackermann*

Tetrahedron, 2013, 69, 4445 - 4453

 

159)  New Advances in Bis(sulfoxides) Chemistry

Sophie Beauvière, Franck Brebion, Saloua Chelli, Bénédicte Delouvrié, Catherine Gomez, Ophélie Kwasnieski, Rocio

Martinez Mallorquin, Francisco Najera, Guillaume Vincent, Maxime R. Vitale, Etienne Derat, Ilan Marek, Max

Malacria, Jean-Philippe Goddard, Louis Fensterbank*

Phosphorus Silicon & Related, 2013, 188, 367 - 376

 

158) Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes via C–H Cleavage

Marvin Schinkel, Ilan Marek and Lutz Ackermann*

Angew. Chem., Int. Ed. 2013, 52, 3977 - 3980

 

157) Alkenyl Zinc reagents in Cross-Coupling Reactions

In Cross-Coupling and Heck-Type Reactions 1 − C-C Cross Coupling Using Organometallic Partners

Tom Mejuch and Ilan Marek*

Science of Synthesis, 2012, 765 - 794


 

156) Forming all-carbon quaternary stereogenic centres in acyclic systems from alkynes

Yury Minko, Morgan Pasco, Lukas Lercher, Mark Botoshansky & Ilan Marek*

Nature, 2012, 490, 522 - 526

 

155) Convergent Diastereoselective Preparation of Adjacent Quaternary Stereocenters in an Acyclic System

Tom Mejuch, Bishnu Dutta, Mark Botoshansky and Ilan Marek*

Organic and Biomolecular Chemistry 2012, 10, 5803 - 5806 (Special issue for 10th Birthday)


 

154) Efficient Brønsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene)cyclopropane

Lutz Ackermann*, Sergei I. Kozhushkov, Dmitry S. Yufit, Ilan Marek

Synlett, 2011, 1515 - 1518

 

153) Combined Carbometalation–Zinc Homologation–Allylation Reactions as a New Approach for Alkoxyallylation of

Aldehyde

Tom Mejuch, Mark Botoshansky, and Ilan Marek*

Org. Lett. 2011, 13, 3604 - 3607 (Selected by Synfact)


 

152 Conjugate Additions to Alkylidene Bis-sulfoxides

Frank Brebion, Guillaume Vincent, Saloua Chelli, Ophelie Kwasnieski, Francisco Najera, Benedicte Delouvrie, Ilan

Marek, Etienne Derat, Jean-Philippe Goddard, Max Malacria*, Louis Fensterbank*

Chem. Asian J. 2011, 6, 1825 - 1833

 

151) Axial Preferences in Allylation via the Zimmerman-Traxler Transition State

Noga Gilboa, Hoa Wang, Ken N. Houk and Ilan Marek*

Chem. Eur. J. 2011, 17, 8000 - 8004

 

150) Carbometalation of Carbon-Carbon Double Bonds in Stereoselective Carbometalations of Carbon-Carbon Double

Bonds.

Ilan Marek* and Ahmad Basheer

Stereoselective Synthesis 1 in Science of Synthesis Ed: J. G. de Vries, 2011, 325 - 408

 

149) Enantioselective Synthesis of all-Carbon Quaternary Stereogenic Centers in Acyclic Systems

Jaya P. Das and Ilan Marek*

Chem. Commun. (Feature article) (2011), 47, 4593-4623.


 

148) Recent Advances in Carbocupration of -heterosubstituted alkynes

Ahmad Basheer and Ilan Marek*

Beilstein J. Org. Chem. (2010), 6, No. 77.


 

147) Regioselective Carbon-Carbon Bond Cleavage in the Oxidation of Cyclpropenylcarbinols

Ahmad Basheer, Massaki Mishima and Ilan Marek*

Org. Lett (2011), 13, 4076-4079.

 

 

146) Selectivity in Metal-Catalyzed Carbon-Carbon Bond Cleavage of Alkylidenecyclopropanes

Ahmad Masarwa and Ilan Marek*

Chem. Eur. J. (2010), 16, 9712-9721


 

145) Diastereo- and Enantioselective Intramolecular Carbometalation Reaction

Rozalia Unger, Theodore Cohen and Ilan Marek*

Tetrahedron (2010), 66, 4874-4881


 

144) Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary

Stereocenters in Acyclic Systems from Simple Terminal Alkynes

Bishnu Dutta, Noga Gilboa and Ilan Marek*

J. Am. Chem. Soc. (2010), 132, 5588-5589


 

143) Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A new Pathway for the Formation of Acyclic

Aldehydes Containing Quaternary Stereogenic Carbons

Samah Simaan and Ilan Marek*

J. Am. Chem. Soc. (2010), 132, 4066-4067


 

142) The Superiority of Properly Prepared Lithium 1-N,N-Dimethylaminonaphthalenide (LDMAN) over Other Aromatic

Radical-anions for the Generation of Organolithiums by Reductive Lithiation

Roman Ivanov, Ilan Marek and Theodore Cohen*

Tetrahedron Lett. (2010), 51, 174-176


 

141) Regiodivergent Carbometalation Reactions of Ynol Ether Derivatives

Anat Levin, Ahmad Basheer and Ilan Marek*

Synlett (2010), 329.


 

140) Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes as a New Approach to the Preparation of

Enantiomerically Pure all-Carbon Quaternary Stereocenters

Samah Simaan, Alex F. G. Golberg, Stephane Rosset and Ilan Marek*

Chem. Eur. J (2010), 16, 774.

[Selected by Synfact]


 

139) Enantioselective preparation of enantiomerically Pure Cyclobutene derivatives

Ahmad Masarwa, Alois Fürstner and Ilan Marek*

Chem. Commun (2009), 5760-5762

[Selected by Synfact]


 

138) Preface for a special issue of Chemistry, A European Journal dedicated to Yitzhak Apeloig

Miri Karni, Ilan Marek, Sason Shaik

Chem. Eur. J. (2009), 15, 8340-8343

 

 

137) Cyclopropenylcarbinol Derivatives: New Versatile Intermediates in Organic Synthesis. Application to the

Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives.

Samah Simaan, Ahmad Masarwa, Elinor Zohar, Amnon Stanger, Philippe Bertus, Ilan Marek*

Chem. Eur. J. (2009), 15, 8449-8464

[Selected as Very Important Paper (VIP)]


 

136) The Basics of Zinc Activation (Perspectives)

Ilan Marek

Science, (2009), 326, 673-674


 

135) Tandem Zn-Brook rearrangement/Ene-Allene Carbocyclization

Rozalia Unger, Theodore Cohen, Ilan Marek*

Eur. J. Org. Chem. (2009), 1749-1756


 

134) Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions

Jaya P. Das, Helena Chechik and Ilan Marek*

Nature Chemistry, (2009), 1, 128-132

[Selected by Synform]

[Highlighted in Angew. Chem. Int. Ed. 2009, 48, 7971 (D. C. Koester, D. B. Werz)]


 

133) Diastereo- and Enantioselective Zinc ene-allene Carbocyclization

Rozalia Unger, Fritz Weisser, Nicka Chinkov, Amnon Stanger, Theodore Cohen and and Ilan Marek*

Org. Lett. (2009), 11, 1853-1856

[Among the 10 most downloaded papers in his first month of parution]

[Selected by Synfact]


 

132) Copper-catalyzed Hydride Transfer Towards the Formation of Alkylidenecyclopropane Derivatives

Samah Simaan and Ilan Marek*

Chem. Commun (2009), 292-294


 

131) Stereoselective Synthesis of Metalated Cyclobutane Derivatives

Einav Tsoglin, Helena Chechik, Guy Karseboom, Nicka Chinkov, Amnon Stanger and Ilan Marek*

Advanced Synthesis and Catalysis (2009), 351, 1005-1008

[Selected by Synfact]


 

130) Zinc Homologation-Elimination Reaction of α-Sulfinyl Carbanions as a New Route to Olefins

Adi Abramovitch and Ilan Marek*

Eur. J. Org. Chem. (2008) 4924-4931

 


129) Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives

Adi Abramovitch, Louis Fensterbank, Max Malacria and Ilan Marek*

Angew. Chem. Int. Ed. (2008) 47, 6865-6868

 

128) A shift in Retrosynthetic Paradigm (Concept article)

Ilan Marek

Chem. Eur. J. (2008), 14, 7460-7468


 

127) Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives

Anat Levin and Ilan Marek*

Chem. Commun. (2008), 4300


 

126) Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition

Bernhard Fuger, Genia Sklute, Ilan Marek, Gae Young Bolm, Carsten Bolm*

Synlett, (2008), 116-118


 

125) Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism

Theodore Cohen*, Heather Gibney, Roman Ivanov, Edmund A.-H. Yeh, Ilan Marek and Dennis P. Curran

J. Am. Chem. Soc. (2007), 129, 15405-15409


 

124) Diastereodivergent Synthesis of Enantiomerically Pure Homoallylic Amine Derivatives Containing Quaternary

Carbon Stereocenters

Goren Kolodney, Genia Sklute, Sylvie Perrone, Paul Knochel and Ilan Marek*

Angew. Chem. Int. Ed. (2007), 46, 9291-9294; Angew. Chem. (2007), 119, 9451-9454.

 

123) An Efficient, Facile and general Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes

Ahmad Masarwa, Amnon Stanger and Ilan Marek*

Angew. Chem. Int. Ed. (2007), 46, 8039-8042; Angew. Chem. (2007), 119, 8185-8188.

 

122) Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis

Ilan Marek*, Samah Simaan, Ahmad Masarwa

Angew. Chem. Int. Ed. (2007), 46, 7364-7376; Angew. Chem. (2007), 119, 7508-7520; (Corrigenda Angew. Chem. Int.

Ed. (2008), 47, 1982; Angew. Chem. (2008), 120, 2008).

 

121) Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions

Ilan Marek* and Genia Sklute

Chem. Commun. (Feature article), (2007) 1683-1691


 

120) Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives

Samah Simaan and Ilan Marek*

Org. Lett. (2007), 9, 2569-2571

[Selected by Synfact]


 

119) Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines

Genia Sklute, Carsten Bolm and Ilan Marek*

Org. Lett. (2007), 9, 1259-1261.

 

 

118) A Zirconium Promenade; A Efficient Tool in organic Synthesis

Ilan Marek*, Nicka Chinkov and Anat Levin

Synlett (account), 501-514 (2006)


 

117) Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions

Genia Sklute and Ilan Marek*

J. Am. Chem. Soc. (2006), 128, 4642-4649

[Selected by Synfact]


 

116) Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives

Samah Simaan, Ahmad Masarwa, Philippe Bertus and Ilan Marek*

Angew. Chem., Int. Ed., (2006), 45, 3963-3965; Angew. Chem. (2006), 118, 4067-4069.


 

115) Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes

Nicka Chinkov, Anat Levin and Ilan Marek*

Angew. Chem., Int. Ed., (2006), 45, 465-468; Angew. Chem. (2006), 118, 479-482.


 

114) New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions

Rozalia Unger, Theodore Cohen and Ilan Marek*

Org. Lett. (2005), 7, 5313-5316


 

113) Special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions

Ilan Marek

Tetrahedron, (2005), 61, 11309-11519. Guest Editors


 

112) Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and

Sulfoxide/Magnesium Exchange Reactions

Felix Kopp, Genia Sklute, Kurt Polborn, Ilan Marek and Paul Knochel*

Org. Lett. (2005), 7, 3789-3791


 

111) Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives

Helena Chechik-Lankin and Ilan Marek*

Synthesis (2005), 3311-3318


 

110) Functionalized Organozirconium and Titanium in Organic Synthesis

In Functionalized Organometallic Derivatives

Ilan Marek* and Helena Chechik-Lankin

Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540


 

109) Regiocontrolled Carbometallation Reactions of Ynamides

Helena Chechik-Lankin, Shulamit Livshin and Ilan Marek*

Synlett (2005), 2098-2100


 

108) Synthesis of Chiral Methylenecyclopropanes Derivatives

Elinor Zohar, Amnon Stanger and Ilan Marek*

Synlett (2005), 2239-2241


 

107) Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condnesation Reactions

Ilan Marek

Isr. J. Chem. (2004), 16, 22-32


 

106) Stereoselective Synthesis and Reactivity of Dienyl Zirconocene

Nicka Chinkov, Swapan Majumbar and Ilan Marek*

Practical Synthetic Procedures Synthesis, (2004), 2411-2417


 

105) New Regio-, Stereo-, Diastereo-, and enantioselective One-Pot Reactions Mediated by Organometallic

Derivatives

Nicka Chinkov, Genia Sklute, Helena Chechik, Adi Abramovitch, Deborah Amsallem, Jos, P. Varghese, Swapan

Majumbar and Ilan Marek*

Pure and Applied Chem. (2004) 76, 517-535

 

104) Stereoselective Synthesis of Dienyl Zirconocenes Complexes

Topic in Organometallic Chemistry

Volume: New Aspects of Zirconium Containing Organic Compounds

Nicka Chinkov and Ilan Marek*

Springer Verlag, (2004), 133-166

 

103) The Preparation of Organolithium Compounds and Derivatives

in The Chemistry of Organolithium Compounds

Frederic Leroux, Manfred Schlosser, Elinor Zohar and Ilan Marek

Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, (2004), 435-493


 

102) Carbometallation Reaction

in Transition Metals for Fine Chemicals and Organic Synthesi-second edition 

Daniella Tene and Ilan Marek*

Eds C. Bolm , M. Beller, Wiley-VCH, (2004), 563-573


 

101) Carbometallation Reaction

in Metal-Catalyzed Cross-Coupling Reactions- second edition

Nicka Chinkov, Daniella Tene and Ilan Marek*

Eds Diederich, F.; de Meijere, A. Wiley-VCH, (2004), 395-478


 

100) Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols
Elinor Zohar, Mirit Ram and Ilan Marek*
Synlett (2004) 1288-1290


99) Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed cross-Coupling Reactions
Stefan Wiedemann, Karsten Rauch, Andrei Savchenko, Ilan Marek, Armin de Meijere*
Eur. J. Org. Chem. (2004) 631-635


98) Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives
Elinor Zohar and Ilan Marek*
Org. Lett. (2004), 6, 341-343

97) α-Sulfinyl Carbanions as A New Source of Olefins
Adi Abramovitch, Jos P. Varghese, Ilan Marek*
Org. Lett. (2004), 6, 621-623


96) From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives
Shahera Farhat, Irena Zouev and Ilan Marek*
Tetrahedron (Special issue on Zirconium Chemistry by invitation only), (2004), 60, 1329-1337


95) Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction
Helena Chechik and Ilan Marek*
Org. Lett. (2003) 5, 5087-5089


94) Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence
Nicka Chinkov, Swapan Majumbar and Ilan Marek*
J. Am. Chem. Soc. 125, 13258-13264, (2003)


93) Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers.
Genia Sklute, Deborah Amsallem, Amal Shibli, Jos P. Varghese and Ilan Marek*
J. Am. Chem. Soc. 125, 11776-11777, (2003)


92) Synthesis and Reactivity of Geminated Organobismetallic Derivatives
Ilan Marek*
Actualite Chimique, special issue on the Present and future in Chemistry, 17-24, (2003) (Invited contribution)


91) Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds
Viet Anh Vu, Ilan Marek, Paul Knochel*
Synthesis, 1797-1802, (2003)


90) Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated η5 Pentadienyl Fe(CO)3 /Fe(CO)2 PPh3(+1) Cations 
Leila Motiei, Ilan Marek, Hugo Gottlieb, Vered Marks and Jean-Paul (Moshe) Lellouche*
Tetrahedron Lett. 44, 5909-5912, (2003)

89) Sp3 Organozinc Carbenoid Homologation in Organic Synthesis
Ilan Marek
Tetrahedron Report, 58, 9463-9475, (2002)

88) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
Nicka Chinkov, Swapan Majumdar, Ilan Marek*
J. Am. Chem. Soc. 124, 10282-10283, (2002)

87) New Preparation of Stereodefined α,β-Unsaturated Ketones by Carbomagnesiation of α-allenyl ketone
Nicka Chinkov, Natalia Morlender-Vais, Ilan Marek*
Tetrahedron lett. 43, 6009-6010, (2002)

86) New Methods for the Preparation of Sp2 Organometallic derivatives
Nicka Chinkov, Helena Chechik, Swapan Majumbar, Annie Liard and Ilan Marek*
Synthesis, Invited review, 2473-2483, (2002)

85) Carbocupration-Zinc Carbenoids Homologation and β-Elimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of Sp3 Organometallic Derivatives
Jos P. Varghese, Irena Zouev, Lionel Aufauvre, Paul Knochel and Ilan Marek*
Eur. J. Org. Chem. 4151-4158, (2002)

84) Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules 
Eike Hupe, Ilan Marek and Paul Knochel*
Org. Lett. 4, 2861-2863, (2002)

 

83) Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides
Stefan Wiedemann, Ilan Marek, Armin de Meijere*
Synlett 879-882, (2002)


82) Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes 
Swapan Majumdar, Armin de Meijere and Ilan Marek*
Synlett 423-426, (2002)


81) From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes
Shahera Farhat and Ilan Marek*
Angew. Chem. Int. Ed. 41, 1410-1413, (2002); Angew. Chem. (2002), 114, 1468-1471

80) Preparation of New Functionalized Cyclopropylmagnesium Reagents 
Viet Anh Vu, Ilan Marek, Kurt Polborn, Paul Knochel*
Angew. Chem. Int. Ed. 41, 351-352, (2002); Angew. Chem. (2002), 114, 361-362


79) Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean F. Normant 
 Ilan Marek
J. Organomet. Chem. 624, 1-3, (2001)


78) Oxidative Addition-β-elimination: A New Method for the preparation of organometallic compounds 
Annie Liard, Helena Chechik, Shahera Farhat, Natalia Morlender-Vais, Claudia Averbuj, Ilan Marek*
J. Organomet. Chem. 624, 26-33, (2001)


77) Diastereoselective Carbozincation of Propargylic Amines 
 Hadi Rezaei, Ilan Marek, Jean F. Normant*
Tetrahedron 57, 2477-2483 (2001)


76) Improved preparation of secondary zinc iodides by 1,2-migration of sp3 carbenoids 
Amal Shibli, Jos P. Varghese, Paul Knochel, Ilan Marek*
Synlett 818-820 (2001)


75) Synthesis and Reactivity of sp2 Geminated Organobismetallics
Ilan Marek
Chem. Rev. 100, 2887-2900 (2000)


74) Carbometalation of unactivated alkynes via low valent titanium derivatives 
Natalia Vais-Morlender, Nicka Solodovnikova, Ilan Marek*
Chem. Commun. 1849-1850 (2000)


73) New Allene Synthesis via Carbocupration- Zinc Carbenoid Homologation and β-elimination
Jos Varghese, Paul Knochel, Ilan Marek*
Org. Lett. 2, 2849-2852 (2000)


72) Stereoselective Preparation of E Vinyl Zirconium Derivatives from E or Z Enol Ether
Annie Liard, Ilan Marek*
J. Org. Chem. 7518-7220, 65, (2000)


71) First Synthesis and reactivity of functionalized alkynyl titanium derivatives 
Natalia Vais-Morlender, Julia Kaftanov and Ilan Marek*
Synthesis, 917-920 (2000) Invited paper


70) Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method
Edwige Lorthiois*, Jean Normant, Ilan Marek
Actual. Chim.(3), 60-61 (2000) Invited paper


69) Synthesis and reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes
Julia Kaftanov, Natalia Vais-Morlender, Claudia Averbuj, Annie Liard, Ilan Marek*
Polyhedron 19, 563-566 (2000) Invited paper

68) New one-pot Synthesis of ω-Iodoalkyne 
Arindam Chakraborty and Ilan Marek*
Synthetic Comm. 30, 1895-1901 (2000)


67) Fluoroform: An efficient precursor for the trifluoromethylation of aldehydes
Benoit Folleas, Ilan Marek, Jean F. Normant*
Tetrahedron 56, 275-283 (2000)


66) Enantioselective Carbometalation of unactivated Olefins
Ilan Marek
J. Chem. Soc. Perkin Trans. 1, 535-544 (1999)


65) Iodine Transfer cyclization mediated by DIBAL-H/THF
Arindam Chakraborty, Ilan Marek*
Chem. Commun. 2375-2376 (1999)


64) A New Approach towards the Synthesis of sp3 1,1-diiodoalkanes
Lionel Aufauvre, Paul Knochel, Ilan Marek*
Chem. Commun, 2207-2208 (1999)


63) First Synthesis of Metallated Titanacyclopropenes 
Claudia Averbuj, Julia Kaftanov, Ilan Marek*
Synlett 11, 1939-1941 (1999)


62) Preparation and Reaction of Functionalized Magnesium Carbenoids
Salvatore Avolio, Christophe Malan, Ilan Marek, Paul Knochel*
Synlett 11, 1820-1822 (1999)


61) The Allyl Zincation of Vinyl Metals. A Computational Study
Ilan Marek, Peter R. Schreiner*, Jean F. Normant
Org. Lett. 1, 929-931 (1999)


60) Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides
Stephanie Norsikian, Ilan Marek*, Sophie Klein, Jean-Francois Poisson, Jean F. Normant*
Chem. Eur. J. 5, 2055 (1999)


59) Diastereoselective contra-Michael addition of (-)-sparteine/organolithium complexes to secondary chiral cinnamyl amides 
Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Tetrahedron Lett. 40, 3383-3386 (1999)


58) Regioselective addition of nbutyllithium on secondary cinnamyl amides Michael versus contra-Michael process 
Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Tetrahedron Lett. 40, 3379-3382 (1999)


57) First Transfer of Chirality in the Fritsch- Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids : A migration with Retention of Configuration
Isabelle Creton, Hadi Rezaei, Ilan Marek*, Jean F Normant*
Tetrahedron Lett. 40, 1899-1902 (1999)


56) Preparation and Reaction of 1,n-bimetallic Reagents in Practical Approach in Organozinc Chemistry
 Ilan Marek, Jean-F Normant
Ed . Knochel, P. Oxford University Press, 119-137 (1998)


55) Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions 
 Ilan Marek, Jean-F Normant
Eds Stang, P.J., Diederich, F. Wiley-VCH, 271-337 (1998)


54) Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis
 Ilan Marek, Jean-F Normant
Eds. Bolm, C., Beller, C. Wiley-VCH, 514-522 (1998)


53) Diastereoselective Carbometalation of Chiral Vinyl Metals 
Denis Brasseur, Ilan Marek*, Jean F. Normant*
C. R. Acad. Sci. Paris, t.1, Serie II c 621-625 (1998)


52) First Diastereoselective carbometalation Of Chiral Vinyl Metals 
Denis Brasseur, Hadi Rezaei, Alain Fuxa, Alex Alexakis, Pierre Mangeney, Ilan Marek*, Jean F. Normant*
Tetrahedron Lett. 39, 4821-4824 (1998)


51) Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds
Benoit Folleas, Ilan Marek*, Jean-F. Normant* and Laurent Saint Jalmes
Tetrahedron Lett. 39, 2973-2976 (1998)


50) Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis 
Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
J. Org. Chem. 63, 2442-2450 (1998)


49) Amino-Zinc-Enolate carbocyclization reactions. New Access to Polysubstituted Piperidines Derivatives 
Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
J. Org. Chem. 64, 566-574 (1998)


48) Enantioselective Carbolithiation of β-alkylated Styrene
Stephanie Norsikian, Ilan Marek*, Jean-F. Normant*
Tetrahedron Lett. 38, 7523-7526 (1997)


47) Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral disubstituted Cyclopropanes 
Stephanie Norsikian, Ilan Marek*, Jean-Francois Poisson, Jean-F. Normant*
J. Org. Chem. 62, 4898-4899 (1997)


46) Zinca-ene-allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines
Edwige Lorthiois, Ilan Marek*, Jean-F. Normant* 
Bull. Soc. Chim. Fr. 134, 333-341 (1997)


45) Zinca-en-allene and Zinc-enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines
Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Tetrahedron Lett. 1997, 38, 89-92 (1997)


44) A Simple and Convenient Method for the Preparation of (Z) or (E)-γ-Iodo Allylics Alcohols and (Z)-β-Iodo Acrolein
Ilan Marek, Christophe Meyer and Jean-F. Normant
Org. Synth. 74, 194-204 (1997)

43) Synthesis and Reactivity of sp3 Geminated Organobismetallics
Ilan Marek* and Jean-F. Normant
Chem. Rev. 96, 3241-3267 (1996)


42) Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2, Organogembismetallics
Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Synthesis 1499-1508 (1996)


41) Intramolecular Carbolithiation of Silylated Enynes
Edwige Lorthiois, Ilan Marek* and Jean-F. Normant*
Tetrahedron Lett. 37, 6693-6694 (1996)


40) Intermolecular Carbolithiation of Silylated Enynes 
Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*

Tetrahedron Lett. 37, 6689-6692 (1996)


39) Diastereoselective Carbometalation of δ-Mono and γ-δ-Disubstituted Z Vinyl Metals
Anja Bahr, Ilan Marek* and Jean-F. Normant*
Tetrahedron Lett. 37, 5873-5876 (1996)

38) Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions
Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Tetrahedron Lett. 37, 857-860 (1996)


37) Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents. Application to a New Propargylmetalation Reaction of Vinyl Metals 
Denis Brasseur, Ilan Marek* and Jean-F. Normant*
Tetrahedron 52, 7235-7250 (1996)


36) Stereoselective Synthesis of Polysubstituted Olefins Via the Formation of 1,1-Bimetalloalkenes
 Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Tetrahedron Lett. 36, 7451-7454 (1995)


35) Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine 
Sophie Klein, Ilan Marek*, Jean Francois Poisson and Jean-F. Normant*
J. Am. Chem. Soc. 117, 8853-8854 (1995)


34) Diastereoselective Reactions of Gembismetallic Derivatives 
Fan Wang, Jie Tang, Lydie Labaudiniere, Ilan Marek* and Jean-F. Normant*
Synlett 723-7251 (1995)


33) Metal-Alkene Π-Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations
 Ilan Marek*, Dov Beruben and Jean-F. Normant*
Tetrahedron Lett. 36, 3695-3698 (1995)


32) Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics
Dov Beruben, Ilan Marek*, Jean-F. Normant and Nicole Platzer
J. Org. Chem. 60, 2488-2501 (1995)


31) Zinca-En-Allene Cyclization. Synthesis of Substituted Tetrahydrofurans 
Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*
Tetrahedron Lett. 36, 1263-1266 (1995)


30) Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis 
Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
J. Org. Chem. 60, 863-871 (1995)


29) Diastereoselective Carbometalation of γ-Heterosubstituted Vinylmetals 
 Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Bull. Soc. Chim. Fr. 131, 910-918 (1994)


28) Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes
Isabelle Creton, Ilan Marek*, Denis Brasseur, Jean-Luc Jestin and Jean-F. Normant*
Tetrahedron Lett. 35, 6873-6876 (1994)


27) Carbocyclization of δ-acetylenic Propargylic Zinc Reagents
Christophe Meyer, Ilan Marek*, Jean-F. Normant and Nicole Platzer*
Tetrahedron Lett. 35, 5645-5648 (1994)


26) Intramolecular Carbometallation of Organozinc Reagents
Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Tetrahedron 50, 11665-11692 (1994)


25) Diastereoselective Carbometalation of Vinyl Metals 
 Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
J. Org. Chem. 59, 4154-6166 (1994)


24) Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn transmetalation and Configurational Stability of Benzylic Organozinc Halides
Sophie Klein, Ilan Marek* and Jean-F. Normant*
J. Org. Chem. 59, 2925-2926 (1994)


23) Cyclic Steocontrol Via Organobismetallic Reagents. Part VI. Stereodefined Substituted Cyclopropyl Zinc Reagents
Dov Beruben, Ilan Marek*, Jean-F. Normant* and Nicole Platzer
Tetrahedron Lett. 34, 7575-7578 (1993)


22) Intramolecular Carbometallation of Secondary Organozinc Reagents 
Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Tetrahedron Lett.34, 6053-6056 (1993)


21) Selective Monoalkylation of Organogembismetallics Via an Intramolecular Nucleophilic Substitution
Fabrice Chemla*, Ilan Marek and Jean-F. Normant*
Synlett 665-666 (1993)


20) (E)-or (Z)-β-iodoacrolein: A Novel Versatile Synthon 
Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Synlett 386-388 (1993)


19) Carbocyclisation of Functionnalized Zinc Organometallics
Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Synlett 266-268 (1993)


18) Cyclic Stereocontrol Via Organobismetallic Reagents. Part V. Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction 
Dov Beruben, Ilan Marek*, Lydie Labaudiniere and Jean-F. Normant*
Tetrahedron Lett. 34, 2303-2306 (1993)


17) Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes 
Alex Alexakis*, Pierre Mangeney, Ilan Marek, Francoise Rose-Munch, Eric Rose, Assia Semra and Francis Robert
J. Am. Chem. Soc. 114, 8288-8290 (1992)


16) Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions
Jean-F. Normant, Ilan Marek and Jean-Michel Lefrancois
Pure and Appl. Chem. 64, 1857-1864 (1992)


15) Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III
 Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Synlett 633-634 (1992)


14) Synthese d'Alcoxyallenes Chiraux par Carbocupration d'Acetals Propargyliques. Etude de Leur Reactivite à l'egard d'Organocuprates
Ilan Marek, Alex Alexakis*, Pierre Mangeney and Jean-F. Normant
Bull. Soc. Chem. Fr. 129, 171-190 (1992)


13) Iodocyclisation of Olefinic t-butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans
Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Tetrahedron Lett. 33, 1747-1748 (1992)


12) γ-tributylstannyl-β-metallated Acrolein: A Versatile Synthon
Ilan Marek*, Alex Alexakis and Jean-F. Normant*
Tetrahedron Lett. 32, 6337-6340 (1991)


11) Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II 
 Ilan Marek* and Jean-F. Normant
Tetrahedron Lett. 32, 5973-5976 (1991)


10) Acyclic Stereocontrol Through the Metalla-Claisen Rearrangement. Part I
Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Tetrahedron Lett. 32, 5969-5972 (1991)


9) A Highly Efficient Synthesis of (Z)-γ-iodo Allylic Alcohols
 Ilan Marek*, Alex Alexakis and Jean-F. Normant
Tetrahedron Lett. 32, 5329-5332 (1991)


8) Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-allenic Alcohols 
 Alex Alexakis*, Ilan Marek, Pierre Mangeney and Jean-F. Normant
Tetrahedron 47, 1677-1696 (1991)

 

7) Mechanistic Aspects on the Formation of Chiral Allenes From propargylic Ethers and Organocopper Reagents
Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant

J. Am. Chem. Soc. 112, 8042-8047 (1990)


6) Structure of 1,3,5-triallyl-4,6-diphenyl-1,3,5-triazacyclohexan-2-one
Jean-P. Declercq* and Ilan Marek
Acta. Cryst., C46, 1168-1170 (1990)


5) Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent 
Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant
Tetrahedron. Lett. 30, 2391-2392 (1989)


4) Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides
Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant
Tetrahedron. Lett. 30, 2387-2390 (1989)


3) Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions
Alex Alexakis*, Pierre Mangeney, Abdellaziz Ghribi, Ilan Marek, Richard Sedrani, Christophe Guir and Jean-F. Normant
Pure & Appl.Chem. 60, 49-56 (1988)


2) Are Allenes formed from Propargylic thers Through a Syn or Anti-Displacement?
Ilan Marek, Pierre Mangeney, Alex Alexakis* and Jean-F. Normant
Tetrahedron Lett. 27, 5499-5502 (1986)


1) Thesis
1988 Ph-D. Thesis from P.M. Curie University, Paris. France
Enantioselective and Diastereoselective Synthesis of Functionalized Allenes